논문초록
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Addressing the inherent challenges of semiconducting single-walled carbon nanotube (s-SWNT) networks, such as roughness and van der Waals gaps, we investigated the enhancement of n-type doped s-SWNT field-effect transistors (FETs). Utilizing anion-π interactions, we achieved high performance s-SWNT-FETs with electron mobility of 39.4 cm2V-1s-1 maintaining high current on/off ratios (>104). The fine-tuned Fermi level was achieved using bilayer doping, resulting in reduced channel and contact resistances, demonstrating improved stability upon bias stress and bending tests. We confirmed the effectiveness of size-selective anion doping in converting s-SWNTs from ambipolar to n-type behavior. The doping effects were systematically revealed by Raman and UV-Vis-nIR spectroscopy. This study offers a novel perspective on enhancing s-SWNT-FETs, highlighting the potential for scalable, high-performance, and flexible electronic devices through strategic anion doping. |